Will Smith Capt. James West Kevin Kline U.S. Marshal Artemus Gordon / President Grant Kenneth Branagh Dr. Arliss Loveless Salma Hayek Rita Escobar M. Emmet Walsh Coleman Ted Levine General 'Bloodbath' McGrath Frederique van der Wal Amazonia Musetta Vander Munitia Sofia Eng Miss Lippenrieder Garcelle Beauvais Belle Bai Ling Miss East Rodney A. Grant Hudson E.J. Callahan Mr. Pinkerton Debra Christofferson Dora Look-Alike Buck Taylor Cross-Eyed Reb James Lashly Reb #1 Dean Rader Duval Reb #2 Orestes Matacena Spanish Dignitary Ian Abercrombie British Dignitary Ismael 'East' Carlo Mexican Dignitary Bob Rumnock White House Aide Gary Carlos Cervantes Dr. Guillermo Escobar J.J. Perry Shovel Guy (uncredited) Dennis Keiffer Wrench Guy (uncredited) Derek Mears Metal Head (uncredited) Will Smith Capt. James West Kevin Kline U.S. Marshal Artemus Gordon / President Grant Kenneth Branagh Dr. Arliss Loveless Salma Hayek Rita Escobar M. Emmet Walsh Coleman Ted Levine General 'Bloodbath' McGrath Frederique van der Wal Amazonia Musetta Vander Munitia Sofia Eng Miss Lippenrieder Garcelle Beauvais Belle Bai Ling Miss East Rodney A. Grant Hudson E.J. Callahan Mr. Pinkerton Debra Christofferson Dora Look-Alike Buck Taylor Cross-Eyed Reb James Lashly Reb #1 Dean Rader Duval Reb #2 Orestes Matacena Spanish Dignitary Ian Abercrombie British Dignitary Ismael 'East' Carlo Mexican Dignitary Bob Rumnock White House Aide Gary Carlos Cervantes Dr. Guillermo Escobar J.J. Perry Shovel Guy (uncredited) Dennis Keiffer Wrench Guy (uncredited) Derek Mears Metal Head (uncredited) Will Smith Capt. James West Kevin Kline U.S. Marshal Artemus Gordon / President Grant Kenneth Branagh Dr. Arliss Loveless Salma Hayek Rita Escobar M. Emmet Walsh Coleman Ted Levine General 'Bloodbath' McGrath Frederique van der Wal Amazonia Musetta Vander Munitia Sofia Eng Miss Lippenrieder Garcelle Beauvais Belle Bai Ling Miss East Rodney A. Grant Hudson E.J. Callahan Mr. Pinkerton Debra Christofferson Dora Look-Alike Buck Taylor Cross-Eyed Reb James Lashly Reb #1 Dean Rader Duval Reb #2 Orestes Matacena Spanish Dignitary Ian Abercrombie British Dignitary Ismael 'East' Carlo Mexican Dignitary Bob Rumnock White House Aide Gary Carlos Cervantes Dr. Guillermo Escobar J.J. Perry Shovel Guy (uncredited) Dennis Keiffer Wrench Guy (uncredited) Derek Mears Metal Head (uncredited)