Milla Jovovich Joan of Arc John Malkovich Charles VII Faye Dunaway Yolande of Aragon Dustin Hoffman Joan's conscience Pascal Greggory The Duke of Alençon Vincent Cassel Gilles de Rais Tchéky Karyo Jean de Dunois Richard Ridings La Hire Desmond Harrington Aulon Timothy West Cauchon Rab Affleck Comrade Stéphane Algoud Look Out David Bailie English Judge David Barber English Judge Timothy Bateson English Judge Christian Barbier Captain Andrew Birkin Talbot Dominic Borrelli English Judge Matthew Bowyer The Bludgeoned French Soldier Paul Brooke Domremy's Priest Bruce Byron Joan's Father Charles Cork Vaucouleurs' Priest Tonio Descanvelle Xaintrailles Philippe du Janerand Dijon Sissi Duparc Mary of Anjou's Lady's Companion Christian Erickson La Tremoille David Gant The Duke of Bedford Robert Goodman Black beard Valerie Griffiths midwife Jacques Herlin the priest of Orleans Michael Jenn The Duke of Burgundy Toby Jones English Judge Richard Leaf Joan's conscience (young men) Joseph Malerba Beaurevoir guard Gina McKee the Duchess of Bedford Phil McKee Red beard Simon Meacock a soldier Quentin Ogier Louis Brian Pettifer the executioner / the torturer of the trial Philip Philmar an english judge Olivier Rabourdin Richemont Vincent Regan Buck Joseph Rezwin Poitiers' Inquisitor Ralph Riach an english judge Julie-Anne Roth a young girl Vincent Tulli Orleans' physicist Jemima West Girl